Electric-car-12v-battery-the-characteristics-and-lithium-battery-development

 

Electric vehicles have two completely different power systems. The main driving system is high voltage, usually 400V-800V, which is the power source of the high-torque motors on the wheels. The other is the 12V power system.

Most electronic equipment in electric vehicles, including infotainment systems, power door locks, power windows, HVAC fans, and safety systems (airbags and ADAS technology), use no more than 12V. This article will give a detailed introduction to the electric car 12v battery.

 

 

 

1. What is electric car 12v battery

The electric car 12v battery plays a key role in automotive applications as a backup power supply, starting battery and output stabilizer. The traditional 12v battery is a lead-acid battery, which is divided into three categories: SLI, EFB and AGM according to the application level and direction, as shown in the table below:

Category

SLI

EFB

AGM

Name

Starting-lighting-ignition battery

Enhanced flooded battery

Absorbent glass mat battery

Function

12V power supply

12V power supply and start and stop

Installed models

Models without start/stop requirements

Mainly installed on Japanese models

Mainly installed on European and American models

Installation location

/

Engine compartment

Normal temperature environment: under the seat or in the trunk

Performance characteristics

Meet the needs of vehicle electrical equipment

High temperature resistance, meet the requirements of start and stop system, high cost performance.

Not resistant to high temperature, excellent start and stop ability, the most advanced battery technology at present

Charging ability

⭐⭐

⭐⭐⭐

Life

⭐⭐

⭐⭐⭐

Price

⭐⭐

⭐⭐⭐

Applicable models

Non-start-stop ordinary models

Non-start-stop ordinary models and entry-level start-stop systems

Non-start-stop ordinary models and all start-stop models

 

For more information, you can click to check the knowledge of agm vs lead acid.

The 12V battery itself has a relatively low voltage, so when used in some scenarios, it generally requires a large current output to achieve high power. Usually 12V batteries pay more attention to battery capacity. Battery capacity can represent both storage capacity and maximum output power, followed by charging capacity, and pulse ability-starting ability based on capacity.

2. Working mode of electric car 12v battery

The main function of the electric car 12v battery is to supply energy to electrical devices and start the engine. Secondly, the auxiliary power supply function requires pulse charging ability. The specific working mode is as the figure below:

Working-mode-of-electric-car-12v-battery

 

3. Application scenarios of electric car 12v battery

Items

ICE

HEV

PHEV

EV

Light mix

Strong mix

Power source

Gasoline

Gasoline+electricity

Electricity

Power supply voltage

12V

48V

≥100V

Output power

2~6kW

5~20kW

≥30kW

Low voltage

12V power supply

12V lead-acid/12V LiB

Engine starting

12V lead-acid/12V LiB

/

Auxiliary power supply

/

LiB

Ni-MH/LiB

LiB

Backup power supply

12V lead-acid/12V LiB

High voltage

Power supply

/

Ni-MH/LiB

LiB

 

4. Functions of electric car 12v battery

Power supply range of electric car 12v battery:

  1. Electrical appliances: Electric car 12v battery supplies power to vehicle electrical appliances, such as: car lights, speakers, screens, etc.
  2. Engine starting: Used for car starting power supply.
  3. Auxiliary power supply: When the generator power is insufficient, the 12V power supply appropriately supplements the power; when the generator power is too high, the 12V power supply stores energy.
  4. Backup power supply: When the on-board 12V fails, the backup power supply is temporarily used to start the vehicle (non-on-board power supply).

5. Lithium-ionization direction of electric car 12v battery

  • Cost of use (product price/service life): Among the three types of electric car 12v lithium battery, EFB and AGM are relatively expensive and have the prospect of being lithium-ionized, while the cost of SLI lithium-ionization is too high.
  • Function: The function of on-board 12V power supply mainly focuses on power supply and engine starting.
  • Power supply: The power of the electric car 12v battery is related to the energy consumption of the electrical equipment under static conditions and the prescribed static power consumption time, and is used in the traditional automobile field and the new energy automobile field.
  • Engine starting: The 12V power supply is related to matching engine starting and is mainly used in traditional automotive fields.
  • Size: The size of the electric car is related to the application field.
  • 12v battery for passenger vehicle models: The size is mainly concentrated at 175mm*190mm (width*height), the length changes with the capacity, and is used by current new energy vehicles.
  • 12V battery for commercial vehicle models: Commercial vehicles have advantages at the installation space and high engine power requirements, and their sizes are relatively variable.
Development-direction-of-electric-car-12v-lithium-battery

6. Lithium-ionization product design

Replacing 12V lead-acid battery:

The size should be consistent with the lead-acid battery, and the performance should reach the power performance of the lead-acid battery. The high-temperature applicability and reduced maintenance cost are the main advantages of the 12v lithium ion battery pack.

New 12V system for new energy vehicle:

Based on the functions mainly focusing on 12V power supply, the high-voltage system automatically recharging the 12V system under static conditions, and the high energy density of the lithium battery itself, the system capacity, power performance and power supply size can be redesigned.

7. Electric car 12v battery lead acid vs lithium iron

Performance

Lithium iron phosphate battery

Lead-acid battery

Cycle life

2500~4000 cls

300~500 cls

High and low temperature resistance

-20~50℃

-5~30℃

Start-stop warranty

About 10 years

≤2 years

Depth of discharge

80%

50%

Power performance

Stable voltage output/low weight/strong power

high voltage in the first half, low voltage in the second half: power weakened at low voltage

Memory effect

No memory effect

With memory effect

Weight comparison of the same specifications

The lead-acid system is 3 to 4 times heavier than the lithium iron phosphate system, and the lithium iron phosphate system is 1.5 to 3 times more expensive than the lead-acid system.

 

Disadvantages of lead-acid batteries

  • Lifespan: The lifespan of lead-acid batteries is not long, and the in-depth development of intelligent 12V vehicle systems has increased the power consumption, further shortening their service life, and the service life is difficult to predict.
  • Environmental concerns: Lead-acid batteries are not environmentally friendly.

The pain points of lithium-ionization

The large-scale application of lithium batteries in the power field has promoted the accelerated iteration of battery technology, and the production cost has continued to decline, providing the possibility to start the lithium electrification of power sources and its large-scale application. Lithium batteries can be used as emergency power when the energy supply of the power system fails.

There are many benefits of using lithium batteries in cars, but lithium electrification still has the following pain points: 

  • Market process: Mainstream electric car companies and traditional car companies still choose lead-acid batteries, and the overall lithium-ionization of electric car 12v battery is progressing slowly.
  • Implementation policy: Lack of targeted policies for electric car 12v battery lithium-ionization.
  • High technical threshold: Low-voltage high-rate batteries require normal operation at -30℃ and meet the high current and high cycle durability required for ICE startup. The technical barriers are very high.
  • Cost barrier: The price of lithium battery version of electric car 12v battery is generally higher than 1,100RMB, which is about 1.5-3 times the price of lead-acid, which is also an important factor hindering the conversion from lead to lithium.

There are few battery manufacturers and few battery products that meet the requirements. At present, only a few car companies such as Tesla, Porsche, BYD, Hyundai, and Kia have started lithium-ionization, and none of them have been promoted on a large scale.

8. Market size of electric car 12v battery

Traditional fuel vehicles

According to statistics, global car sales in March 2021 were 229 million vehicles. If all 12V starting power supplies are replaced by lithium batteries, the corresponding annual demand for lithium batteries will reach 68.7GWh (average power 300Wh/car).

New energy vehicles

According to predictions by relevant organizations, global electric vehicle sales will reach 15 million units in 2025. Global electric vehicle sales will reach 23 million units in 2030. If the 12V vehicle power supply uses LFP battery to replace lead-acid batteries, the installed battery capacity will be 100-500wh/car.

Calculated based on the battery capacity of 300wh/car, the proportion of LFP replacing lead-acid batteries in 2025 will be 10%, corresponding to the 12V system lithium battery demand of approximately is 0.45GWh. If the replacement ratio is 50% in 2030, the corresponding 12V system lithium battery demand will reach 3.45GWh.

Forecast of 12V market demand in the global new energy vehicle market

Year

Global new energy vehicle market sales (10,000 units)

12V lithium battery capacity (wh/vehicle)

LFP replacing lead-acid ratio

Annual demand for 12V lithium batteries (GWh)

2025

1500

300

10%

0.45

2030

2300

300

50%

3.45

2030

2300

300

100%

6.9

Note: 1. New energy vehicles include passenger cars and commercial vehicles. 2. The current battery power is concentrated at 100-500wh/car. The above data is calculated based on 300Wh.

 

9. Technical requirements for electric car 12v lithium battery

  • Charge and discharge rate: (pulse) charging 30C, discharging 40C
  • Lifespan: In line with the high-voltage system of new energy vehicles, battery life is required to be ≥10 years and the number of starts and stops is ≥200,000 times
  • High temperature performance: The 12V battery is installed in the engine compartment, and the internal temperature can reach above 80℃, so the maximum temperature that the 12V car battery can withstand is ≈80℃
  • Consistency: Since electric car 12v lithium battery is discharged at a high rate, defects are infinitely magnified and will affect the overall performance, so the requirements for consistency are high and the terminal car battery voltage difference is required to be <50mV.
Technical-requirements-for-electric-car-12v-lithium-battery

    10. Industry layout of electric car 12v lithium battery

    • CATL: Developed a 12v lithium battery auxiliary power supply that is 80% lighter and 60% smaller than traditional lead-acid batteries.
    • EVE Energy: Jaguar Land Rover and Daimler have designated 12v projects. In February 2021, EVE Energy planed to invest 2.6 billion RMB each to build the "xHEV battery system project (Phase I)". The project content is 12V and 48V battery systems.
    • Wanxiang A123: Wanxiang began to develop the first-generation 12v starter battery in 2011, mass-produced the second-generation Nano-LFP in 2013, and the third-generation was mass-produced in 2017. Currently, the focus of considering the fourth-generation 12v battery is how to make the cost lower.
    • Camel Group: The 12v low-voltage lithium battery is in contact with a number of European and American high-end car companies and has passed technical review and business negotiations. Related products are as follows:

    LFP

    CATL

    BYD

    BYD

    EVE

    Camel

    Camel

    A123

    A123

    Type

    Cylindrical

    Square

    Square

    Square

    Soft pack

    Soft pack

    Soft pack G2

    Soft pack G3

    System

    LFP/Gr

    LFP/Gr

    LFP/Gr

    LFP/Gr

    LFP/Gr

    LFP/Gr

    Nano-LFP/Gr

    Ultra-LFP/Gr

    Capacity

    20Ah

    20Ah

    10Ah

    22Ah

    20Ah

    30Ah

    20Ah

    20Ah

    Nominal voltage

    3.2V

    3.2V

    3.2V

    3.22V

    3.2V

    3.2V

    3.3V

    3.3V

    Dimension/mm

    46*145

    /

    /

    17*148*128

    /

    /

    ?*161*227

    14.2*150*144

    Energy density

    121Wh/kg

    /

    /

    116Wh/kg

    /

    /

    /

    125Wh/kg

    Lifespan

    >8000 cls 25℃@70%

    >3000 cls 25℃1C/1C @80%

    >3000 cls 25℃1C/1C @80%

    90000Ah(Disc.)

    (System 8 years)

    (System 8 years)

    /

    /

    Service temperature range

    -30~65℃

    -29℃~

    /

    -40~60℃

    /

    /

    /

    /

    Application field

    12V system

    12V system

    12V system

    12V system

    12V system

    12V system

    12V system

    12V system

    Development status

    /

    2021.Q4

    2021.Q4

    /

    2022.Q1

    2023.Q1

    2013.SOP

    2017.SOP

     

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